STAINLESS STEEL INFO
“What you need to know”
(Probably more then you ever wanted to
know!)
The following are some terms and their definitions you will encounter
when dealing with stainless steel.
18-8: 300
series stainless steel having approximately (not exactly) 18% chromium
and 8% nickel. The term "18-8" is used interchangeably to characterize
fittings made of 302, 302HQ, 303, 304, 305, 384, XM7, and other variables
of these grades with close chemical compositions. There is little
overall difference in corrosion resistance among the "18-8" types, but
slight differences in chemical composition do make certain grades more
resistant than others do against particular chemicals or atmospheres.
"18-8" has superior corrosion resistance to 400 series stainless, is generally
nonmagnetic, and is hardenable only by cold working.
304: The
basic alloy. Type 304 (18-8) is an austenitic steel possessing a minimum
of 18% chromium and 8% nickel, combined with a maximum of 0.08% carbon.
It is a nonmagnetic steel which cannot be hardened by heat treatment, but
instead. must be cold worked to obtain higher tensile strengths.
The 18% minimum chromium content provides
corrosion and oxidation resistance. The alloy's metallurgical characteristics
are established primarily by the nickel content (8% mm.), which also extends
resistance to corrosion caused by reducing chemicals. Carbon, a necessity
of mixed benefit, is held at a level (0.08% max.) that is satisfactory
for most service applications.
The stainless alloy resists
most oxidizing acids and can withstand all ordinary rusting. HOWEVER, IT
WILL TARNISH. It is immune to foodstuffs, sterilizing solutions, most of
the organic chemicals and dyestuffs, and a wide variety of inorganic chemicals.
Type 304, or one of its modifications, is the material specified more than
50% of the time whenever a stainless steel is used.
Because of its ability to withstand
the corrosive action of various acids found in fruits, meats, milk, and
vegetables, Type 304 is used for sinks, tabletops, coffee urns, stoves,
refrigerators, milk and cream dispensers, and steam tables. It is also
used in numerous other utensils such as cooking appliances, pots, pans,
and flatware.
Type 304 is especially suited
for all types of dairy equipment - milking machines, containers, homogenizers,
sterilizers, and storage and hauling tanks, including piping, valves, milk
trucks and railroad cars. This 18-8 alloy is equally serviceable in the
brewing industry where it is used in pipelines, yeast pans, fermentation
vats, storage and railway cars, etc. The citrus and fruit juice industry
also uses Type 304 for all their handling, crushing, preparation, storage
and hauling equipment.
In those food processing applications
such as in mills, bakeries, and slaughter and packing houses, all metal
equipment exposed to animal and vegetable oils, fats, and acids is manufactured
from Type 304.
Type 304 is also used for the
dye tanks, pipelines buckets, dippers, etc. that come in contact with the
lormic, acetic, and other organic acids used in the dyeing industry.
In the marine environment, because
of it slightly higher strength and wear resistance than type 316 it is
also used for nuts, bolts, screws, and other fasteners. It is also
used for springs, cogs, and other components where both wear and corrosion
resistance is needed.
Type Analysis of Stainless Type 304
| Carbon |
0.08% max. |
Silicon |
1.00% max. |
| Manganese |
2.00% max. |
Chromium |
18.00-20.00% |
| Phosphorus |
0.045% max. |
Nickel |
8.00-10.50% |
| Sulfur |
0.030% max. |
|
|
|
316:
For severe environments. Of course, there are many industrial processes
that require a higher level of resistance to corrosion than Type 304 can
offer. For these applications, Type 316 is the answer.
Type 316 is also austenitic, non-magnetic,
and thermally nonhardenable stainless steel like Type 304. The carbon content
is held to 0.08% maximum, while the nickel content is increased slightly.
What distinguishes Type 316 from Type 304 is the addition of molybdenum
up to a maximum of 3%.
Molybdenum increases the corrosion resistance of this
chromium-nickel alloy to withstand attack by many industrial chemicals
and solvents, and, in particular, inhibits pitting caused by chlorides.
As such, molybdenum is one of the single most useful alloying additives
in the fight against corrosion.
By virtue of the molybdenum addition,
Type 316 can withstand corrosive attack by sodium and calcium brines, hypochlorite
solutions, phosphoric acid; and the sulfite liquors and sulfurous acids
used in the paper pulp industry. This alloy, therefore, is specified for
industrial equipment that handles the corrosive process chemicals used
to produce inks, rayons, photographic chemicals, paper, textiles, bleaches,
and rubber. Type 316 is also used extensively for surgical implants within
the hostile environment of the body.
Type 316 is the main stainless used
in the marine environment, with the exception of fasteners and other items
where strength and wear resistance are needed, then Type 304 (18-8) is
typically used.
Type Analysis of Stainless Type 316:
| Carbon |
0.08% max. |
Silicon |
1.00% max. |
| Manganese |
2.00% max. |
Chromium |
16.00-18.00% |
| Phosphorus |
0.045% max. |
Nickel |
10.00-14.00% |
| Sulfur |
0.030% max. |
Molybdenum |
2.00-3.00% |
|
AN: Stands
for Air Force-Navy.
ANSI: Stands
for American National Standards Institute.
ASME: Stands
for American Society of Mechanical Engineers.
ASTM: Stands
for American Society of Testing and Materials.
AIRCRAFT QUALITY:
Fittings made with a particularly high level of attention in manufacture
and inspection.
ANNEAL:
To heat metal in order to lower its hardness. The term anneal refers
to the heat treatment given all 300 series stainless and most 400 series
stainless by the steel mill after the raw material has been completed but
before fittings are manufactured. Anneal also refers to the heat
treatment given 400 series stainless fittings after their manufacture (also
called hardening and tempering) to lower hardness and increase toughness.
For example, fittings of 410 stainless may score over 200,000 psi after
manufacture and be too brittle. By annealing at 1000 degrees F.,
tensile strength would reduce to 125,000-150,000 psi, while annealing the
same material to 500 degrees F. would bring tensile to 160,000-190,000
psi.
BL: Stands
for "Break Load", meaning the weight at which a product will break.
ELONGATION:
Stretching a fitting to the point that it breaks. The percent of
elongation at rupture (same as measure of ductility) is determined by dividing
to total length after stretching to the original length. Elongation
decreases as strength and hardness increase.
GALVANIC CORROSION:An
accelerated degree of corrosion occurring when two different metals are
in contact with moisture, particularly seawater. All metals have
what is termed a specific electric potential, so that low-level electric
current flows from one metal to another. A metal with a higher position
in the galvanic series (see below) will corrode sacrificially rather than
one with a lower position, meaning stainless, for example, will corrode
before gold. The further apart the metals on the chart, the more
electric current will flow and the more corrosion will occur. No
serious galvanic action will occur by combining the same metals only dissimilar
ones. To prevent galvanic corrosion, use insulation, paint or coatings
when separating dissimilar metals; or put the metal to be protected next
to a metal which is not important in the assembly, so it can corrode sacrificially.
The metals listed at the top of the table below will corrode first due
to galvanic reaction before those at bottom of the table.
Galvanic Corrosion Table
Most Corrodable
|
Magnesium
|
|
Zinc
|
|
Aluminum 1100
|
|
Cadmium
|
|
Aluminum 2024
|
|
Steel and Iron
|
|
Lead
|
|
Tin
|
|
Brass
|
|
Copper
|
|
Bronze
|
|
Monel
|
|
304 Stainless Steel
|
|
316 Stainless Steel
|
|
Silver
|
|
Titanium
|
|
Graphite
|
|
Gold
|
Least Corrodable
|
ISO: Stands
for International Organization for Standardization.
MS: Stands
for Military Standards. The overriding characteristic of MS fittings
compared to commercial products is the extensive inspection and lot traceability
for MS, guaranteeing the chemical, physical and dimensional qualities.
While commercial fittings may look similar and happen to pass many tests
given MS products, the commercial fittings lack the pedigree of guaranteed
quality or chemical, physical and dimensional aspects that users who order
MS fittings rely on.
MAGNETIC PERMEABILITY:
Test simply determines the level of magnetism.
MARINE QUALITY: This
term differs depending on the application.Fittings and hardware
are usually made of Type 316 stainless to resist corrosion. They are usually
highly polished. Nuts bolts, screws, and other fasteners and items where
strength and wear are required are usually made of Type 304 (18-8).
MOLYBDENUM: Nicknamed
moly, molybdenum is a metal added to 316 stainless steel, sharply increasing
its corrosion resistance to chlorides and sulfates especially various sulfurous
acids in the pulp industry. Molybdenum helps reduce hardness and
increase tensile strength at higher temperatures.
MONEL: Invented
by the International Nickel Co., and composed basically to two-thirds nickel,
one-third copper. Monel has good strength, excellent corrosion resistance
against salt water and in high temperatures, and is very expensive.
PASSIVATING:
A very confusing term, since the common usage has taken on a different
meaning that the technical definition. In SUNCOR's experience, users
(including engineers) of commercial fittings seldom mean the old technical
terminology. Technically, passivation is not cleaning but is a process
of dipping fittings into a nitric acid solution to rapidly form a chromium
oxide on the surface of the material, creating a passive film that protects
stainless from further oxidation (see PASSIVE FILM). The purpose
of passivation is to remove both grease left from manufacturing and traces
of steel particles that may have rubbed off manufacturing tools onto the
fitting. In common commercial parlance (meaning non-military and
aerospace), passivating means cleaning to users, and the terms "passivating"
and "cleaning" are used interchangeably. A wide range of cleaning
methods using different mixtures containing nitric, phosphoric and other
acids or simply exposing cleaned stainless fittings to air for a period
of time will result in a "passivated" condition. For fittings that
have been properly cleaned, it is impossible to determine the method of
cleaning or passivation that was used. AN/MS/NAS fittings sold by
SUNCOR have been cleaned, descaled, and passivated to the applicable engineering
specifications.
PASSIVE FILM:
The major characteristic of stainless is its ability to form a thin layer
of protection called a "passive film" on its outside surface. This
film results from a continual process of low-level oxidation, so oxygen
from the atmosphere is needed for the passive film to exist. Once
formed, it prevents further oxidation or corrosion from occurring.
Even if chipped or scratched, a new passive film on stainless will form.
PICKLING:
Removing surface impurities by using chemicals.
PITTING CORROSION:
Pitting indicates deep corrosion in localized spots on a fastener.
Dirt or grease on certain portions of a fastener may block oxygen from
that surface, thus impeding the passsive film that protects stainless from
corrosion.
PROOF LOAD:
A test load that a fitting must undergo without showing significant deformation.
It is usually 90% that of yield strength.
SOLUTION ANNEALED
(same as CARBIDE SOLUTION ANNEALED) : A process of heating and removing
carbide precipitants (carbon that has broken loose from its stainless steel
solution) by heating a finished fitting to over 1,850 degrees F. and cooling
it quickly, usually in water, so carbon content goes back into the stainless
solution.
THREAD:
Class 1 threads are a loose tolerance. Class 2 threads comprise 90%
of stainless fittings and are normal commercial tolerance. Class
3 threads have a stricter tolerance and tighter fit such as socket cap
and set screws. No definite relationship exists between tensile strength
and tightness or looseness of fit. The symbol "A" added to threads,
such as 2A, means external threads (screws), and "B" means internal (nuts).
WLL:
Stands for "Work Load Limit", this is the recommended weight limit for
safe use of a product.
Bosun Supplies Inc.
PO Box 86, Arnold, MD 21012
Phone: 888-433-3484 Fax: 410-431-7008
info@bosunsupplies.com
Check out our STAINLESS STEEL CHAIN!.
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